(MEC 2700)




Table of Items

Experiment you: Heat Capability of Smells

Experiment two: Thermal and Electrical Conductivity of Alloys Experiment a few: Heat Pump

Experiment some: Heat Louage

Experiment five: Free and compelled Convection

Try things out 6: Energy Radiation

Research 1: Heat Capacity of Gases


The first rules of thermodynamics can be illustrated particularly well with a perfect gas. This law explains the relationship between your change in inside intrinsic strength О”Ui the heat exchanged while using surroundings О”Q and the constant-pressure change pdV.

dQ = dUi & pdV (1)

The molar heat capability C of your substance comes from the amount of absorbed heat plus the temperature modify per skin mole:


n = volume of moles

One differentiates involving the molar high temperature capacity in constant amount CV plus the molar warmth capacity at constant pressure Cp.

In respect to equations (1) and (2) and under isochoric conditions (V const., dV = 0), the following is true:


and under isobaric conditions (p = const., dp sama dengan 0):


Taking the equation of express for great gases into consideration:

pV = n 3rd there’s r T (5)

it employs that the difference between Cp and CV for ideal gases is definitely equal to the universal gas constant 3rd there’s r.

Cp – CV sama dengan R (6)

It is clear from equation (3) the fact that molar temperature capacity CV is a function of the inside intrinsic strength of the gas. The internal energy can be computed with the aid of the kinetic gas theory through the number of degrees of freedom f:



kilobytes = 1 . 38 В· 10-23 J/K (Boltzmann Constant)

NA sama dengan 6. 02 В· 1023 mol-1 (Avogadro's number)

Through substitution of

R = kB EM (8)

it follows that


and taking formula (6) into account:


The number of examples of freedom of any molecule is known as a function of its composition. All debris have several degrees of translational freedom. Diatomic molecules offer an additional two degrees of rotating freedom about the principal axes of masse. Triatomic elements have 3 degrees of revolving freedom. Air consists generally of o2 (approximately 20%) and nitrogen (circa 80%). As a initial approximation, the following can be thought to be authentic for surroundings:

n = five

CV sama dengan 2 . five R

CV = twenty. 8 T В· K-1 В· mol-1


Cp = three or more. 5 Ur

Cp = 29. 1 J В· K-1 В· mol-1.

installment payments on your OBJECTIVE

The experiment should determine the molar heat capacities of air at constant volume Cv with constant pressure Cp.

several. EQUIPMENT

Finely-detailed manometer


Digital counter-top

Digital multimeter

Aspirator bottle (10000 ml)

Gas syringe (100 ml)

Stopcock, 1-way and 3-way

Rubber arreter, d = 32/26 logistik, 3 slots

Rubber stopper, d sama dengan 59. 5/50. 5 logistik, 1 hole

Rubber tubing, d sama dengan 6 mm

Nickel electrode

Chrome-nickel wire

Push-button change


Part A – Determining the Constant Value Cv

i) The set up is as shown in Figure 1 .

ii) To determine Cv, connect the accurate manometer towards the bottle having a piece of hoses. The manometer should be located exactly flat. Pressure enhance has to be go through immediately after the heating process. iii) Begin the measuring procedure by pressing the push switch switch. The measuring period should be not more than a second. iv) Take blood pressure measurements of the pressure (from the manometer), the existing and volts. v) Take away the air from the aspirator bottle of wine after every single measurement. vi) Repeat measures iii) to v) to be able to obtain twelve sets of results. Differ О”t in the given selection.

Part N – Identifying the Constant Benefit Cp

i) The setup is as shown in Physique 2 .

ii) Replace the precision manometer with two...


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